Hi,
It’s true that adding dimensions to Rows in the metric set means you’re grouping by those values in that order, and this multi-dimensional way that metric sets work is the same regardless of what visualization you’re using and continues after re-visualizing. There is currently no option available for when you want to “break” this grouping, so to effectively sort by ExtPrice values without any grouping you would instead need to group by a column/dimension made up of unique values.
If your data source contains any other column besides OrderNo & LineNo that is unique, it could be added first under Rows in the metric set so that you aren’t grouping by non-unique order numbers. If there isn’t and there is nothing identifying each row of this data other than the combination of order and line numbers, creating a hierarchy from the main menu allows you to add both OrderNo and LineNo as Member Key Source (click Add Key when setting up a level to add a 2nd key) so that it’s made up of the OrderNo-LineNo pair of values, and would not group only by order numbers if it’s added first under Rows. If it hasn’t been raised yet with Support we do have a feature request we can add you to for a way to sort by measure without grouping by any dimension, but right now you would instead need to group first by any dimension of unique values.